Evaluation of lab lab extract (Lablab purpureus) as an antioxidant additive to biodiesel
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Abstract
There is a growing interest in advancing the development of biofuels, with biodiesel entering the Brazilian national market. The oxidative stability of biodiesel, or induction period (IP), is one of the important factors for determining the quality of this biofuel, thus allowing its commercialization and ensuring its validity during storage. Biodiesel is formed by methyl or ethyl esters with the presence of unsaturations from the raw material used in the synthesis, making it susceptible to the oxidation reaction. Natural extracts are replacing antioxidant additives of synthetic origin. This research aimed to evaluate the influence of adding lab lab leaves extract as a natural antioxidant additive on the oxidative stability of biodiesel and kinetic parameters. Samples containing extract showed higher induction periods and lower rate constants when compared to the control in the test at a temperature of 110°C. Since the leaves have low costs, lab lab extract with antioxidant properties has potential for commercial application to increase the oxidative stability of biodiesel.
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References
AKBARIRAD, H., ARDABILI, A. G., KAZEMEINI, S. M., & KHANEGHAH, A. M. An overview on some of important sources of natural antioxidants. International food research journal, v. 23, n. 3, 2016. (http://www.ifrj.upm.edu.my/23%20(03)%202016/(3).pdf)
ALARA, O. R.; ABDURAHMAN, N. H.; UKAEGBU, C. I.l. Extraction of phenolic compounds: A review. Current research in food science, v. 4, p. 200-214, 2021. (doi.org/10.1016/j.crfs.2021.03.011)
ANOUAR, E.; KOŠINOVÁ, P.; KOZLOWSKI, D.; MOKRINI, R.; DUROUX, J. L.; TROUILLAS, P. New aspects of the antioxidant properties of phenolic acids: a combined theoretical and experimental approach. Physical chemistry chemical physics, v. 11, n. 35, p. 7659-7668, 2009. (doi.org/10.1039/b904402g)
AKBARIRAD, H.; ARDABILI, A. G.; KAZEMEINI, S. M.; KHANEGHAH, A. M. An overview on some of important sources of natural antioxidants. International food research journal, v. 23, n. 3, 2016. (http://ifrj.upm.edu.my/23%20(03)%202016/(3).pdf)
BRANCO, I. G.; CAMPOS, J. W.; SILVA, N. F.; CLEMENTE, M. A. J.; MANTOVANI, A. C. G.; CHENDYNSKI, L. T.; BORSATO, D. Mathematical modeling of the biodiesel oxidation process in the presence of natural ethanolic extracts of jabuticaba peels, gabiroba leaves, and hibiscus flowers. Química Nova, v. 47, p. e-20230090, 2024. (doi.org/10.21577/0100-4042.20230090)
BRASIL. RESOLUÇÃO, ANP Nº. 798, Agência Nacional do Petróleo, Gás Natural e Biocombustíveis de 01.08. 2019–DOU 02.08. 2019
BENÍCIO, L. P. F.; MOREIRA, V. F; LIMA, S. D. O.; PEREIRA, A. J.; RODRIGUES, H. V. M.. Productivity of aboveground and protein value forage legume species, cultured in the cerrado tocantinense.2011.
CALEGARI, A. Perspectivas e estratégias para a sustentabilidade e aumento da biodiversidade em sistemas agrícolas com o uso de adubos verdes. In: LIMA FILHO, O. F. et al. (ed) Adubação verde e plantas de cobertura no Brasil: fundamentos e prática. Brasília, DF: Embrapa, 2014. 1 v. p 21 - 36. Cap. 01. (ISBN 978-65-86056-63-1 v. 1/ https://www.embrapa.br/busca-de-publicacoes/-/publicacao/1161208/adubacao-verde-e-plantas-de-cobertura-no-brasil-fundamentos-e-pratica-volume-1)
CLEMENTE, M. A., MARCHEAFAVE, G. G., BRANCO, I. G., CANESIN, E. A., MANTOVANI, A. C. G., CHENDYNSKI, L. T.,BORSATO,, D. (2023). Study of the addition of Gabiroba leaves extract in the biodiesel oxidation reaction in the presence of metal ions. Biofuels, 1-6. (doi.org/10.1080/17597269.2023.2191388)
CHENDYNSKI, L. T., ROMAGNOLI, É. S., MANTOVANI, A. C. G., KIMURA, M., MARQUES, L. C., & BORSATO, D. Influence of copper and metallic alloys on the oxidation reaction of commercial biodiesel in mixture with natural antioxidant. Journal of the Brazilian Chemical Society, v. 30, p. 90-96, 2019. (doi.org/10.21577/0103-5053.20180157 )
CORREIA, I. A. S.; BORSATO, D.; SAVADA, F. Y.; PAULI, E. D., MANTOVANI, A. C. G., CREMASCO, H.; CHENDYNSKI, L. T. Inhibition of the biodiesel oxidation by alcoholic extracts of green and black tea leaves and plum pulp: Application of the simplex-centroid design. Renewable Energy, v. 160, p. 288-296, 2020. (doi.org/10.1016/j.renene.2020.06.118)
DEL RÉ, P. V.; JORGE, N. Spices as natural antioxidants: their application in food and implication for healt. Revista Brasileira de Plantas Medicinais. v. 14, p. 389-399, 2012. (doi.org/10.1590/S1516-05722012000200021)
EUROPEAN COMMITTEE FOR STANDARDIZATION. EN 14112: Determination of oxidation stability (accelerated oxidation test). 2016.
EUROPEAN COMMITTEE FOR STANDARDIZATION. EN 14214: Automotive fuels. Fatty acid methyl esters (FAME) for diesel engines-Requirements and test methods. 2019.
GAO,Y; MA, S.; WANG, M.; FENG, X.-Y. Characterization of free, conjugated, and bound phenolic acids in seven commonly consumed vegetables. Molecules, v. 22, n. 11, p. 1878, 2017. (doi.org/10.3390/molecules22111878)
GRASEL, F. S.; FERRÃO, M. F.; WOLF, C. R.. Ultraviolet spectroscopy and chemometrics for the identification of vegetable tannins. Industrial Crops and Products, v. 91, p. 279-285, 2016.(doi.org/10.1016/j.indcrop.2016.07.022)
GREGÓRIO, A. P. H.; ROMAGNOLI, E. S.; BORSATO, D.; GALVAN, D.; SPACINO, K. R. Kinetic and thermodynamic parameters in biodiesel oxidation reaction in the presence of coffee leaves and sage extracts. Sustainable Energy Technologies and Assessments, v. 28, p. 60-64, 2018.(doi.org/10.1016/j.seta.2018.06.008)
HAMINIUK, Charles WI et al. Phenolic compounds in fruits–an overview. International Journal of Food Science & Technology, v. 47, n. 10, p. 2023-2044, 2012. (doi.org/10.1111/j.1365-2621.2012.03067.x)
JEYAKUMAR, N., HUANG, Z., BALASUBRAMANIAN, D., LE, A. T., NGUYEN, X. P., PANDIAN, P. L., & HOANG, A. T. Experimental evaluation over the effects of natural antioxidants on oxidation stability of binary biodiesel blend. International Journal of Energy Research, 2022.(doi.org/10.1002/er.7956)
KUMAZAWA, S., HAMASAKA, T., & NAKAYAMA, T. Antioxidant activity of propolis of various geographic origins. Food chemistry, v. 84, n. 3, p. 329-339, 2004.(doi.org/10.1016/S0308-8146(03)00216-4)
MANTOVANI, A. C. G.; CHENDYNSKI, L. T.; GALVAN, D.; BORSATO, D.; MAURO, E. D. Evaluation of the oxidation degradation process of biodiesel via 1H NMR spectroscopy. Journal of the Brazilian Chemical Society, v. 31, p. 1661-1667, 2020. (doi.org/10.21577/0103-5053.20200052)
MIYAGUSUKU-CRUZADO, Gonzalo et al. Monitoring hydroxycinnamic acid decarboxylation by lactic acid bacteria using high-throughput UV-Vis spectroscopy. Molecules, v. 25, n. 14, p. 3142, 2020.(doi.org/10.3390/molecules25143142)
MIYAGUSUKU-CRUZADO, Gonzalo et al. High yield production of cyanidin-derived pyranoanthocyanins using 4-vinylphenol and 4-vinylguaiacol as cofactors. Food Chemistry, v. 427, p. 136705, 2023.(doi.org/10.1016/j.foodchem.2023.136705)
MURPHY, A. M.; COLUCCI, P. E. A tropical forage solution to poor quality ruminant diets: A review of Lablab purpureus. Livestock Research for Rural Development, v. 11, n. 2, p. 1999. (https://lrrd.cipav.org.co/lrrd11/2/colu112.htm)
NAEEM, M. et al. Lablab bean (Lablab purpureus L.)—An untapped resilient protein reservoir. Neglected and Underutilized Crops, p. 391-411, 2023.(doi.org/10.1016/B978-0-323-90537-4.00018-1)
ROMAGNOLI, É. S., BORSATO, D., SILVA, L. R. C., CHENDYNSKI, L. T., ANGILELLI, K. G., & CANESIN, E. A. Kinetic parameters of the oxidation reaction of commercial biodiesel with natural antioxidant additives. Industrial Crops and Products, v. 125, p. 59-64, 2018. (doi.org/10.1016/j.indcrop.2018.08.077)
SANTOS, W. P.; RIBEIRO, N. M.; GERREIRO, E. S.; NANO, R. M.; BENEVIDES, C. M.; LOPES, M. V.; MIRANDA, K. E. Prospecção tecnológica de leguminosas na produção de alimentos funcionais destinados ao setor de panificação e confeitaria. Cadernos de Prospecção, v. 10, n. 4, p. 919-919, 2017. (doi.org/10.9771/cp.v10i4.23091)
SILVA, S. dos A. B. E.; SILVA, M. S. L da, FERREIRA, G. B. Produção e composição nutricional de espécies para cobertura do solo. In: REUNIÃO BRASILEIRA DE MANEJO E CONSERVAÇÃO DO SOLO E DA ÁGUA, 16., 2006, Aracaju. Resumos e palestras... Aracaju: SBCS; UFS: Embrapa Tabuleiros Costeiros, 2006. Disponível em: < https://www.alice.cnptia.embrapa.br/alice/bitstream/doc/157472/1/OPB938.pdf>. Acesso: 27 jun. 2021
SILVA, E. D.; ROCHA MATOS, H. R.; BARROS, B. G. A.; DE OLIVEIRA, F. J. V. Esterco caprino na composição de substratos para germinação e emergência de Lablab purpureus. Scientific Electronic Archives, v. 15, n. 1, 2022. (doi.org/10.36560/15120221505)
SIMIONI, T.A. et al. Potencialidade da consorciação de gramíneas e leguminosas forrageiras em pastagens tropicais. PUBVET, Londrina, v. 8, n. 13, ed. 262, Art. 1742, jul., 2014. (doi.org/10.22256/pubvet.v8n13.1742)
SOUSA, L. S.; DE MOURA, C. V. R.; DE OLIVEIRA, J. E.; DE MOURA, E. M.L. Use of natural antioxidants in soybean biodiesel. Fuel, v. 134, p. 420-428, 2014. (doi.org/10.1016/j.fuel.2014.06.007)
SOUSA, L. S; DE MOURA, C. V. R; DE MOURA, E. M. Influence of binary, ternary and quaternary mixtures on oxidative stability and study of kinetics and thermodynamic parameters of the degradation process of soybean biodiesel. Fuel, v. 259, p. 116235, 2020.(doi.org/10.1016/j.fuel.2019.116235)
SPACINO, K. R., DA SILVA, E. T., ANGILELLI, K. G., MOREIRA, I., GALAO, O. F., & BORSATO, D. Relative protection factor optimisation of natural antioxidants in biodiesel B100. Industrial Crops and Products, v. 80, p. 109-114, 2016. (doi.org/10.1016/j.indcrop.2015.11.034)
SUI, M.; CHEN, Y.; LI, F.; WANG, H. Study on transition metal ion Fe3+ catalyzed biodiesel oxidation and inhibition mechanism. Fuel, v. 303, p. 121288, 2021.(doi.org/10.1016/j.fuel.2021.121288)
TANIGUCHI, Kenkichi et al. Conversion of benzyl phenyl ether to monoaromatics in high-temperature aqueous ethanol solution under high-pressure carbon dioxide conditions. New Journal of Chemistry, v. 47, n. 27, p. 12561-12569, 2023. (doi.org/10.1039/D3NJ01773G)
WITT, E. D. P.; JOHANN, G.; TRIQUES, C. C.; DA SILVA, E. A.; SILVA, C.; BORSATO, D.; DA SILVA BAUMGARTNER, T. R. (2022). Potential application of supercritical extract of pomegranate peel as bio‐antioxidant for biodiesel. Environmental Progress & Sustainable Energy, v. 41, n. 2, p. e13755, 2022. (doi.org/10.1002/ep.13755)
WUTKE, E. B.; CALEGARI, A.; WILDNER, L. P. Espécies de adubos verdes e plantas de cobertura e recomendações para seu uso. In: LIMA FILHO, O. F. et al. (ed) Adubação verde e plantas de cobertura no Brasil: fundamentos e prática. Brasília, DF: Embrapa, 2014. v.1, p 59 - 167. Cap. 03. (ISBN 978-65-86056-63-1 v. 1/ https://www.embrapa.br/busca-de-publicacoes/-/publicacao/1161208/adubacao-verde-e-plantas-de-cobertura-no-brasil-fundamentos-e-pratica-volume-1)